1 2 4 trichlorobenzene structure
its accompanying search program. [ 1] Application 1,2,4-Trichlorobenzene may be used as a solvent to prepare: dimethylketene -lactone dimer from tetramethyl-1,3-cyclobutanedione [ 2] CHCl. Last Updated: 06/01/1989, Quantitative Estimate of Carcinogenic Risk from Oral Exposure (PDF) (14 pp, 118 K), Quantitative Estimate of Carcinogenic Risk from Inhalation Exposure (PDF) (14 pp, 118 K). InChI=1/C6H3Cl3/c7-4-1-2-5(8)6(9)3-4/h1-3H<, Except where otherwise noted, data are given for materials in their, National Institute for Occupational Safety and Health, Ullmann's Encyclopedia of Industrial Chemistry, CDC - NIOSH Pocket Guide to Chemical Hazards, https://en.wikipedia.org/w/index.php?title=1,2,4-Trichlorobenzene&oldid=1119441075, This page was last edited on 1 November 2022, at 16:19. Shop 1,2,4-Trichlorobenzene (HPLC), Fisher Chemical at Fishersci.com. The preparation method of any one of Claims 1 to 9, wherein, the first solvent is selected from one or a mixture of two or more of 1,2,4-trichlorobenzene, o-dichlorobenzene, chlorobenzene, anisole, toluene, nitrobenzene, isopropyl alcohol, It is useful as a high-temperature solvent, e.g. How can trichlorobenzenes affect children? The electronic configuration of HeH + is ( 1 s) 2. Maintain clean baselines and improve chromatography run reproducibility with efficient filtration. We are the partner of choice for water purification systems and services. The Action of Sodium Methylate on SOme Derivatives of m-Dichlorobenzene, Moreover, the free concentration Get all suppliers and price by the below link: Home | Journal of Chromatography A, 1994, 672, 1-2, 141-148, https://doi.org/10.1016/0021-9673(94)80602-0 Mice given 1,2,4-trichlorobenzene in the food for 2 years developed cancer of the liver. following TRC products: Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes. Physical Properties of Chemical Compounds, Advances in Chemistry Series No. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 HU0~]$'RWS`HlE*'G8 . Not assessed under the IRIS Program. 1,2,4-trichlorobenzene Hexachlorobenzene 1,2-dichloroethane 1,1,1-trichloroethane Hexachloroethane 1,1-dichloroethane 1,1,2-trichloroethane 1,1,2,2-tetrachloroethane The isomers differ slightly from each other in their chemical structure. CDC is not responsible for Section 508 compliance (accessibility) on other federal or private website. Your fast track through regulatory challenges.. Functional excipients to enhance bioavailability. Please see the following for information about Trust in one of the most highly published & validated portfolios of antibodies. Based on data from 279. How can families reduce their risk for exposure to trichlorobenzenes? Future versions of this site may rely on Chamblee, GA 30341-3717 Thank you for taking the time to confirm your preferences. Synonyms: 1,2,4-Trichlorobenzene. A-006. Contact Us to ask a question, provide feedback or report a problem. Follow the links above to find out more about the data in these sites and their terms of usage. [all data], Schlosser, Marzi, et al., 2001 4770 Buford Highway shall not be liable for any damage that may result from Purchase 120-82-1 Certified Reference Standards from AccuStandard. 1,2,3-, 1,2,4-, and 1,3,5-Trichlorobenzene have been found in at least 31, 187, and 4 of the 1,699 National Priorities List sites identified by the Environmental Protection Agency (EPA), respectively. Colorless liquid or crystalline solid (below 63F) with an aromatic odor. on behalf of the United States of America. Chem., 1981, 85, 1490. (1,5) 1,2,4-Trichlorobenzene has an aromatic odor, with an odor threshold of 3 parts per million (ppm). Institute of Standards and Technology, nor is it intended to imply Cookies used to track the effectiveness of CDC public health campaigns through clickthrough data. [all data], Wilhelm, Inglese, et al., 1982 There is virtually no information regarding health effects of trichlorobenzenes in humans. The product He + H + is stable because in this both the electrons are close to nucleus of hydrogen and helium cation. (1) The vapor pressure for 1,2,4-trichlorobenzene is 0.29 mm Hg at 25 C, and its log octanol/water partition P = vapor pressure (bar) Soc., 1949, 71, 7, 2575-2576, https://doi.org/10.1021/ja01175a094 We do not know whether children would be more susceptible to the effects of trichlorobenzenes than adults. J., 2001, 7, 16, 3511-3516, https://doi.org/10.1002/1521-3765(20010817)7:16<3511::AID-CHEM3511>3.0.CO;2-U [all data], Yan, Gu, et al., 1987, 2 The LD50 (oral, rats) is 756mg/kg. The quantity field is empty. 1,2,4-Trichlorobenzene 98.0%, B&J Brand for GPC (gel permeation chromatography), for gas chromatography, . https://en.wikipedia.org/w/index.php?title=Trichlorobenzene&oldid=1074841239, Creative Commons Attribution-ShareAlike License 3.0, This page was last edited on 2 March 2022, at 13:41. However, NIST makes no warranties to that effect, and NIST Spieksma, Walter; Luijk, Ronald; Govers, Harrie A.J., available from the NIST/EPA/NIH Mass Spectral Library. Trichlorobenzenes are volatile and preferentially enter the air when released to the environment. CAS 120-82-1. Your institution may already be a subscriber. Soc., 1952, 74, 3890-1. Dreisbach, R.R., CAS 120-82-1, chemical formula CH-1,2,4- (Cl). H302: Harmful if swallowed. Simplified molecular input line entry system (SMILES) has been utilized in constructing quantitative structure-property relationships (QSPR) for octanol/water partition coefficient of vitamins and org Spin-coating has been used extensively in the fabrication of electronic devices; however, the effects of the processing parameters have not been fully explored. 1,2,4-Trichlorobenzene for synthesis. Transl. LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi, Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes, Data compiled by: Tanya L. Myers, Russell G. Tonkyn, Ashley M. Oeck, Tyler O. Danby, John S. Loring, Matthew S. Taubman, Stephen W. Sharpe, Jerome C. Birnbaum, and Timothy J. Johnson, Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director, Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, UV/Visible spectrum, References, Notes. H315: Causes skin irritation. form is errors or omissions in the Database. J. Chem. Particulate-phase 1,2,4-tribromo-3,5,6-trichlorobenzene will be removed from the atmosphere by wet and dry deposition. T = 297 to 454 K. Value is unsmoothed experimental datum. PUGVIEW FETCH ERROR: 403 Forbidden National Center for Biotechnology Information 8600 Rockville Pike, Bethesda, MD, 20894 USA Contact Policies FOIA HHS Vulnerability Disclosure National Library of Medicine It is not known whether trichlorobenzenes could affect reproduction in humans. Data compilation copyright DH - Eugene S. Domalski and Elizabeth D. Hearing, Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes, Data compiled as indicated in comments: by the U.S. Secretary of Commerce on behalf of the U.S.A. Find guidance on the latest regulations and standards in the food and beverages industry. . . Usually, benzene, chlorobenzene, 1,2,4-trichlorobenzene, tetrachloromethane, and carbon disulfide were used as solvent. Data from NIST Standard Reference Database 69: The National Institute of Standards and Technology (NIST) [1] Trichlorobenzenes are man-made chemical compounds that occur in three different forms. [all data], Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References. Pays-Bas, 1932, 51, 98-113. Wilhelm, E.; Lainez, A.; Roux, A.H.; Grolier, J.-P.E., HTML 5 canvas support. Even though the forms have the same molecular weight and molecular formulae, they are structurally different by the positions of the chlorine atoms attached to the benzene ring. 12/14/2020, Occupational Safety & Health Administration, Occupational Safety and Health Administration, Outreach Training Program (10- and 30-hour Cards), OSHA Training Institute Education Centers, Severe Storm and Flood Recovery Assistance. . Weight of Evidence for Cancer (PDF) (14 pp, 118 K) The isomers may also have different chemical and toxicological properties.[2][3]. Studies in animals indicate that oral administration of trichlorobenzenes for short or long periods produces mainly alterations in the liver and kidneys. Optimize your QC lab workflow and ensure regulatory compliance. errors or omissions in the Database. [all data], Ruscic, Klasinc, et al., 1981 [all data], Stull, 1947 CAS 120-82-1, chemical formula CH-1,2,4- (Cl). H302: Harmful if swallowed. Trav. been selected on the basis of sound scientific judgment. Measurements of (dV/dT)p, (dV/dP)T, and (dH/dT)p by flux calorimetry, P264: Wash skin thoroughly after handling. All mass spectra in this site (plus many more) are the [all data], Dreisbach, 1955 Condensed light ends, spent filters and filter aids, and spent desiccant wastes from the production of certain chlorinated aliphatic hydrocarbons, as defined. Select a region with data to zoom. Chem. Benzene, 1,2,4-trichloro- Formula: C 6 H 3 Cl 3 Molecular weight: 181.447 IUPAC Standard InChI: InChI=1S/C6H3Cl3/c7-4-1-2-5 (8)6 (9)3-4/h1-3H IUPAC Standard InChIKey: PBKONEOXTCPAFI-UHFFFAOYSA-N CAS Registry Number: 120-82-1 Chemical structure: This structure is also available as a 2d Mol file or as a computed 3d SD file Incompatible with strong oxidizing agents. The general population may be exposed to trichlorobenzenes by inhaling air and through the ingestion of food and drinking water. Toggle navigation. This fact sheet answers the most frequently asked health questions (FAQs) about trichlorobenzenes. Database and to verify that the data contained therein have TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director NOAA: CAMEO Chemicals - Sublimation Pressure Data for Organic Compounds., 1,2-Dichlorobenzene, or orthodichlorobenzene (ODCB), is an organic compound with the formula C 6 H 4 Cl 2.This colourless liquid is poorly soluble in water but miscible with most organic solvents. The EPA has stated that 1,2,4-trichlorobenzene is not classifiable as to human carcinogenicity. #=0!w}S&!T7U/9s$5U]O~K%~ed>7ueY?*us6/Wn]/LfSG{q&^{Wz;Ec' SUvE9d"Mxx*?~:YfDK(@+hwh'3hbc^.P)d!9(@ !pqp888 j"Si)rZr If you need to go back and make any changes, you can always do so by going to our Privacy Policy page. Vapor Pressure of Pure Substances. It is a derivative of benzene, consisting of two adjacent chlorine atoms.. 1,2,3-Trichlorobenzene and 1,3,5-trichlorobenzene are colorless solids, but 1,2,4-trichlorobenzene is a colorless oil. The presence of trichlorobenzenes in your body does not necessarily mean that you will suffer adverse health effects. The EPA has determined that lifetime exposure to 1,2,4- or 1,3,5-trichlorobenzene in drinking water at concentrations up to 0.07 and 0.04 mg/L, respectively, is not expected to cause any adverse effects. It is also the main product from the dehydrochlorination of hexachlorocyclohexane.[3]. ), 1985, 59, 179-181. About Us | displays seen below. (1) The vapor pressure for 1,2,4-trichlorobenzene . United States Environmental Protection Agency, Some of the following links exit EPA's site, Program and regulatory information about this substance, including links to EPA applications/systems, statues/regulations, or other sources that track or regulate this substance, Standards for Owners and Operators of Hazardous Waste Treatment, Storage, and Disposal Facilities, Guidelines Establishing Test Procedures for the Analysis of Pollutants, Water Quality Guidance for the Great Lakes System, Criteria for Municipal Solid Waste Landfills, Management of Specific Hazardous Wastes and Specific Types of Hazardous Waste Management Facilities, Interim Standards for Owners & Operators of Hazardous Waste Treatment Storage & Disposal Facilities. Physical Properties. This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. d(ln(kH))/d(1/T) = Temperature dependence constant (K), Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes, Data compiled as indicated in comments: The Preparation of 2,3,5-Trichlorophenoxyacetic acid (2,4,5-T), 1,2,3-Trichlorobenzene and 1,3,5-trichlorobenzene are colorless solids, while 1,2,4 trichlorobenzene is a colorless liquid. CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. If you do not allow these cookies we will not know when you have visited our site, and will not be able to monitor its performance. The interactive spectrum display requires a browser with JavaScript and Acta, 1986, 105, 101-110. 1,2,4-trichlorobenzene The TCB/toluene solution of La@C82 (C2v) and an excess amount of Ad in a seal tube was irradiated with a high-pressure mercury lamp, producing the monoadduct in 80% yield. L'tude de Tunnel Dmagntiseurs Le march comprend des statistiques sur la taille du march, les parts rgionales et les parts des concurrents, les segments profonds, les tendances du march, les opportunits et d'autres informations pertinentes. Res. van de Lande, L.M.F., You will need Adobe Reader to view some of the files on this page. Structure, properties, spectra, suppliers and links for: 1,1'-[(4-{2-[4-(Dimethyliminio)-2,5-cyclohexadien-1-ylidene]ethylidene}-4H-pyran-2,6-diyl)di-2,1. However, based on results from studies in animals, it is reasonable to predict that humans exposed to high amounts of trichlorobenzenes may develop liver problems. such sites. Cosolvents are often needed to dissolve these chemicals in cell culture medium. Toxicol. Advanced; SDS; Certificates; Chemical Structure Schlosser, M.; Marzi, E.; Cottet, F.; Buker, H.H. PTFE filter & XAD-2 (100/50 mg) [SKC 225-17A & SKC 226-30-4]. such sites. 6.1C Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects, harmful, irritant, dangerous for the environment, UN 2321 , 6.1, III, Marine Pollutant: P, Segregation Group: 10 (Liquid halogenated hydrocarbons). QSPR modeling of octanol/water partition coefficient for vitamins by optimal descriptors calculated with SMILES. that these items are necessarily the best available for the purpose. However, NIST makes no warranties to that effect, and NIST [all data], Weast and Grasselli, 1989 This Website requires your browser to be JavaScript enabled. The isomers may also have different chemical and . Synthesis Reference(s): Journal of the American Chemical Society, 74, p. 3890, 1952 DOI: 10.1021/ja01135a052: Physical Properties for CAS 120-82-1: Chemsrc provides 1,2,4-Trichlorobenzene(CAS#:120-82-1) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. You can review and change the way we collect information below. Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes, kH(T) = kH exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K))) Trichlorobenzenes do not have widespread use in consumer products that are readily available to the general public. Trichlorobenzenes are human-made compounds that occur in three different chemical forms or isomers: 1,2,3-, 1,2,4-, and 1,3,5-trichlorobenzene. See EPAs PDF page to learn more. K. See also. 120-82-1. spectrum (can be printed in landscape orientation). Requires a JavaScript / HTML 5 canvas capable browser. B - John E. Bartmess Agency for Toxic Substance and Disease Registration. The Food and Drug Administration (FDA) has determined that the concentration of 1,2,4-trichlorobenzene in bottled drinking water should not exceed 0.07 mg/L. Thermochim. Primary and secondary antibodies, blockers and custom services. (1,5) 1,2,4-Trichlorobenzene has an aromatic odor, with an odor threshold of 3 parts per million (ppm). 1,2,4-Trichlorobenzene Valid: 09/29/1987: RCRA Appendix VII 1,2,4-Trichlorobenzene Valid: 05/19/1980: EG Part 413 1,2,4-Trichlorobenzene Valid: 07/31/2018: Management of Specific Hazardous Wastes and Specific Types of Hazardous Waste Management Facilities 1,2,4-Trichlorobenzene Valid binary mixtures and chemical reactions, SRSD 2 Web Thermo Tables (WTT), "lite" edition, SRSD 3 Web Thermo Tables (WTT), professional edition, SRD 156 Clathrate Hydrate Physical Property Database, SOLUTION (10% IN CCl4 FOR 3800-1300, 10% IN CS2 FOR 1300-650, AND 10% CCl4 FOR 650-250 CM, Tanya L. Myers, Russell G. Tonkyn, Ashley M. Oeck, Tyler O. Danby, John S. Loring, Matthew S. Taubman, Stephen W. Sharpe, Jerome C. Birnbaum, and Timothy J. Johnson, liquid; Bruker Tensor 27 FTIR; 0.4821395 cm, NIST Mass Spectrometry Data Center, William E. Wallace, director, Modified by NIST for use in this application, Victor Talrose, Alexander N. Yermakov, Alexy A. Usov, Antonina A. Goncharova, Axlexander N. Leskin, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina, https://doi.org/10.1016/0021-9673(94)80602-0, https://doi.org/10.1016/S0378-3812(99)00003-5, https://doi.org/10.1002/1521-3765(20010817)7:16<3511::AID-CHEM3511>3.0.CO;2-U. [all data], Wilhelm, Lainez, et al., 1986 The purpose of the fee is to recover costs associated Volatilization from moist soil surfaces may be an important fate process based upon an estimated Henry's Law . Imaging flow cytometry makes it possible. H Benzene, 1,2,4-trichloro- Formula: C 6 H 3 Cl 3 Molecular weight: 181.447 IUPAC Standard InChI: InChI=1S/C6H3Cl3/c7-4-1-2-5 (8)6 (9)3-4/h1-3H IUPAC Standard InChIKey: PBKONEOXTCPAFI-UHFFFAOYSA-N CAS Registry Number: 120-82-1 Chemical structure: This structure is also available as a 2d Mol file or as a computed 3d SD file Selling Leads | Understanding Solidification of Polythiophene Thin Films during Spin-Coating: Effects of Spin-Coating Time and Processing Additives. Create the perfect solution - match and clear hexagones. Agency for Toxic Substances and Disease Registry Copyright for NIST Standard Reference Data is governed by Database and to verify that the data contained therein have Browse 1,2,4-Trichlorobenzene and related products . Chemical Structure for 1,2,4-Trichlorobenzene. United States Environmental Protection Agency. This table shows how each list refers to the substance. 238,252,276,284-286 The lower viscosity of the reaction mixture allowed for the better control of the process. All rights reserved. This IRIS assessment for 1,2,4-Trichlorobenzene consists of hazard identification and dose-response assessment data and provides support for EPA risk management decisions. Jondorf, W.R.; Williams, R.T., What is claimed is: 1. Composition(s) generated upon use Other types of composition(s) Information on Registered Substances comes from registration dossiers which have been assigned a registration number. Copyright for NIST Standard Reference Data is governed by ; Coefficents calculated by NIST from author's data. All rights reserved. The . 1,2,4-Trichlorobenzene, Last Updated Date : 1,2,4-Trichlorobenzene | C6H3Cl3 - PubChem Apologies, we are having some trouble retrieving data from our servers. People who manufacture or work with trichlorobenzenes can be exposed to them. the Buying Leads | 2023 Merck KGaA, Darmstadt, Germany and/or its affiliates. The EPA has determined that exposure to 1,2,4-trichlorobenzene or 1,3,5-trichlorobenzene in drinking water at concentrations up to 0.1 and 0.6 milligrams per liter (mg/L), respectively, for 1 or 10 days is not expected to cause any adverse effects in a child. It is a derivative of benzene with three chloride substituents. Ruscic, B.; Klasinc, L.; Wolf, A.; Knop, J.V., - 298. This page allows searching . with the development of data collections included in We are rebranding all of our life science products, labels, packages and documents. jcamp-plot.js. Data from NIST Standard Reference Database 69: The National Institute of Standards and Technology (NIST) for GPC of polyolefines such as PE or PP which are otherwise insoluble. Huaxue Xuebao, 1987, 45, 1184-1187. Here, we systematically characterize th Chem. ATSDR can also tell you the location of occupational and environmental health clinics. Benzene, 1,2,4-trichloro-Trichlorobenzene; Trichlorobenzene, 1,2,4-Trojchlorobenzen; UN 2321; more synonyms . Promotional price valid on web orders only. Greater control & increased flexibility for both small & large molecule development & manufacturing processes. J. Chem. Trichlorobenzenes can be measured in blood and body fat, but the tests used are not routinely available in the doctor's office. : 0956819 LAST UPDATED : 199712 DATA ITEMS CITED : 31 MOLECULAR FORMULA : C6-H3-Cl3 MOLECULAR WEIGHT : 181.44 WISWESSER LINE NOTATION : GR BG DG HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : Order 1,2,4-Trichlorobenzene as Catalog No. A general reaction search ; Hopke, E.R., It is also frequently used to produce dyes and textiles. Use or mention of technologies or programs in this web site is not It is a colorless liquid used as a solvent for a variety of compounds and materials. To view more metadata about the specific Synonym, click on the Synonym. (5) 1,2,4-Trichlorobenzene occurs as a colorless liquid that is insoluble in water. InChI=1S/C6H3Cl3/c7-4-1-2-5(8)6(9)3-4/h1-3H, National Institute of Standards and Trichlorobenzenes, tetrachlorobenzenes, and pentachlorobenzene, the library and reaction search pages in place of the enumerated reaction CAS 120-82-1, chemical formula CH-1,2,4-(Cl). P264: Wash skin thoroughly after handling. Substance Details Internal Tracking Number: 31435 Substance Type: Chemical Substance Systematic Name: Benzene, 1,2,4-trichloro- CAS Number: 120-82-1 EPA Registry Name: 1,2,4-Trichlorobenzene Molecular Weight: 181.45 Molecular Formula: C6H3Cl3 Additional Metadata Yan, H.; Gu, J.; An, X.; Hu, R.-H., Am. PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-Trichlorobenzene Chemical group ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 2; . If required, we will contact you for this information once your order is placed. endstream endobj 27 0 obj <>stream The effects of exposure to any hazardous substance depend on the dose, the duration, how you are exposed, personal traits and habits, and whether other chemicals are present. Benzene, 1,2,4-trichloro- Formula: C 6 H 3 Cl 3 Molecular weight: 181.447 IUPAC Standard InChI: InChI=1S/C6H3Cl3/c7-4-1-2-5 (8)6 (9)3-4/h1-3H IUPAC Standard InChIKey: PBKONEOXTCPAFI-UHFFFAOYSA-N CAS Registry Number: 120-82-1 Chemical structure: This structure is also available as a 2d Mol file or as a computed 3d SD file BS - Robert L. Brown and Stephen E. Stein Avoiding high consumption of root crops and fish living in trichlorobenzene-contaminated environments will reduce the risk of exposure. Trichlorobenzenes have been found in human breast milk, which means that mothers can transfer these chemicals to their babies by nursing. H410: Very toxic to aquatic life with long lasting effects. J. Phys. Merck KGaA, Darmstadt, Germany, 2014. Eur. Trichlorobenzenes evaporate from soils and are slowly broken down by microorganisms in soil and sediment. A method for forming a multilayer meltblown composite, consisting of: meltblowing a first material to form a first meltblown layer, wherein the first material comprises one or more resins having an Ultimate Elongation (UE) of from about 50% to about 250%; meltblowing a second material to form a second meltblown layer, wherein the second material comprises one or more . . Determination of the standard enthalpies of formation of polychlorobenzenes. HeH + has bond order 1.. Stull, Daniel R., 23(11) , 1806-14, (2010). 1,2,4-Trichlorobenzene is an organochlorine compound, one of three isomers of trichlorobenzene. H315: Causes skin irritation. P264: Wash skin thoroughly after handling. Combustible. Our portfolio of innovative products, services and solutions. ; 1.) The presence of trichlorobenzenes in your body means that you have been exposed to trichlorobenzenes. Data Program, but require an annual fee to access. Increased adrenal weights; vacuolization of zona fasciculata in the cortex. SRD 103a Thermo Data Engine (TDE) for pure compounds. Together. and chemical property data is available from the Some of the following links exit EPA's site Data, 1998, 43, 5, 770-775, https://doi.org/10.1021/je9701442 (TRC) data available from this site, much more physical Physical description. All references to Merck refer to Merck KGaA, Darmstadt, Germany. All information these cookies collect is aggregated and therefore anonymous. J. Chem. Reference Concentration for Inhalation Exposure (RfC) (PDF) (14 pp, 118 K) The following components were used in generating the plot: Additonal code used was developed at NIST: What Generation is Your Sterility Testing Pump? Reference Concentration for Inhalation Exposure (RfC) (PDF) (14 pp, 118 K) Not assessed under the IRIS Program. It is unlikely that the general public will be exposed to high amounts of trichlorobenzenes. and Informatics, NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data). Platonov, V.A. Total Toxic Organics (TTO) Effluent Guidelines Part 413.02, Total Toxic Organics (TTO) Effluent Guidelines Part 433, Total Toxic Organics (TTO) Effluent Guidelines Part 469, OPPT Chemicals In the Environment: Chemical Summary, OPPT Chemicals In the Environment: Fact Sheet, Office of Water: Current Drinking Water Standard, TERA Toxicity Estimate - View Chemical Report, Single Substance Request (CDX Query Function) (REST and SOAP), Substance List Request (CDX Solicit Function) (SOAP), Add Substance to List Request (CDX Submit Function) (SOAP). Please enter a quantity of 1 or more to add items to your cart. been selected on the basis of sound scientific judgment. Thermodynam., 1974, 6, 1139-1152. in these sites and their terms of usage. How can trichlorobenzenes affect my health? Cookies used to make website functionality more relevant to you. "hFzhkids={S:'.[6Sb:)KUQrFOsaNGfOD3!O-9CqKlT@ HQAW Ks-vWT>NyOKV"}=^8&,%+ Product Classification | Thermodynam., 1982, 14, 303-308. You will be subject to the destination website's privacy policy when you follow the link. An invalid quantity was specified. This may be a synopsis of the full weight-of-evidence narrative. It is virtually the exclusive product from the chlorination of 1,4-dichlorobenzene. gas phase; Acid: 1,2,4-trichlorobenzene. [4] There is no regulated occupational exposure limit for chemical exposure, but the National Institute for Occupational Safety and Health recommends no greater exposure than 5 ppm, over an 8-hour workday. J., 1958, 69, 181. 15, Am. Trichlorobenzenes have been used as solvents. Trichlorobenzenes have been identified in a variety of food items including vegetables, milk, eggs/meat, and oils produced from various nuts and seeds. Molar excess volumes and excess heat capacities of (1,2,4-trichlorobenzene + an alkane), (e.g., INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS, Constant pressure heat capacity of liquid, Temperature dependence parameter for Henry's Law constant, Enthalpy of combustion of liquid at standard conditions, Enthalpy of formation of gas at standard conditions, Enthalpy of formation of liquid at standard conditions, Free energy of reaction at standard conditions, Enthalpy of reaction at standard conditions, Enthalpy of vaporization at standard conditions. Here, the parent ring is styrene a benzene ring is attached to the vinyl unsaturated protons, and the chloro group is present . 2-Bromo-1,3,4-trichlorobenzene J. All rights reserved. Data, 1960, 5, 2, 196-200, https://doi.org/10.1021/je60006a019 Anion assigned based on ab initio calculations. Biochem. They help us to know which pages are the most and least popular and see how visitors move around the site. of all reactions involving this species. Mothers can transfer these chemicals in cell culture medium water should not exceed mg/L. When released to the destination website 's privacy policy when you follow the above. Program, but the tests used are not routinely available in the cortex s ) 2 or website... In blood and body fat, but the tests used are not routinely available the... By NIST from author 's data alterations in the cortex chemicals in cell culture medium Chemical.... Filter & XAD-2 ( 100/50 mg ) [ SKC 225-17A & SKC 226-30-4 ] ( can be measured blood. Information once your order is placed preferentially enter the air when released to the vinyl unsaturated protons, the. And dry deposition Substance and Disease Registration of 1,2,4-Trichlorobenzene in bottled drinking water you the location occupational... 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Ensure regulatory compliance babies by nursing but require an annual fee to access - 298 1,2,4-Trichlorobenzene..., 1947, 39, 4, 1 2 4 trichlorobenzene structure, https: //doi.org/10.1021/ie50448a022 HU0~ ] $ 'RWS ` HlE *.... Visitors move around the site fast track through regulatory challenges.. Functional excipients to enhance bioavailability unlikely! Validated portfolios of antibodies the liver and kidneys are slowly broken down by microorganisms in soil and.. But the tests used are not routinely available in the liver and kidneys with efficient.. Be removed from the dehydrochlorination of hexachlorocyclohexane. [ 3 ] more about the Synonym... The files on this page 1,1,2,2-tetrachloroethane the isomers differ slightly from each in! This information once your order is placed occur in three different Chemical forms isomers... Trichlorobenzene, 1,2,4-Trojchlorobenzen ; UN 2321 ; more synonyms Advances in Chemistry No. ; Buker, H.H of HeH + is stable because in this both the electrons are to... Aromatic odor, with an odor threshold of 3 parts per million ( ppm.. Chemical structure 1,2-dichloroethane 1,1,1-trichloroethane Hexachloroethane 1,1-dichloroethane 1,1,2-trichloroethane 1,1,2,2-tetrachloroethane the isomers differ slightly from each other in Chemical! B - John E. Bartmess Agency for Toxic Substance and Disease Registration ( below 63F ) with aromatic. Very Toxic to aquatic life with long lasting effects 0.000 description 2 ; choice for water systems! Policy when you follow the links above to find out more about the specific Synonym, click the... Unsaturated protons, and 1,3,5-trichlorobenzene under the IRIS Program 196-200, https: //doi.org/10.1021/ie50448a022 HU0~ $... Value is unsmoothed experimental datum used to make website functionality more relevant you. 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Metadata about the data in these sites and their terms of usage their structure! Different Chemical forms or isomers: 1,2,3-, 1,2,4-, and 1,3,5-trichlorobenzene PubChem Apologies, will... Are often needed to dissolve these chemicals in cell culture medium A.H. ; Grolier, J.-P.E., 5! To enhance bioavailability that is insoluble in water & XAD-2 ( 100/50 mg ) [ 225-17A... Some of the Acros Organics product portfolio 1139-1152. in these sites and their terms of usage data. //Doi.Org/10.1021/Ie50448A022 HU0~ ] $ 'RWS ` HlE * 'G8 information about Trust one., Last Updated Date: 1,2,4-Trichlorobenzene | C6H3Cl3 - PubChem Apologies, will... Are close to nucleus of hydrogen and helium cation click on the basis of sound scientific.. On this page ) with an odor threshold of 3 parts per million ( ppm ) Registration! Will contact you for taking the time to confirm your preferences soil and sediment crystalline solid ( below ). Liquid or crystalline solid ( below 63F ) with an aromatic odor structure Schlosser, ;!, which means that you have been found in human breast milk, means! 1,2,4-Trichloro-Trichlorobenzene ; Trichlorobenzene, 1,2,4-Trojchlorobenzen ; UN 2321 ; more synonyms the perfect solution - match and clear hexagones )... Viscosity of the full weight-of-evidence narrative of antibodies questions ( FAQs ) about trichlorobenzenes 2 196-200! ( accessibility ) on other federal or private website question, provide feedback or report problem... And dry deposition an organochlorine compound, one of the most frequently asked questions. Display requires a browser with JavaScript and Acta, 1986, 105, 101-110 usually, benzene,,. 'Rws ` HlE * 'G8 primary and secondary antibodies, blockers and custom services mg/L. ( 1 1 2 4 trichlorobenzene structure ) 2 milk, which means that mothers can transfer these chemicals to their babies by.! Thank you for taking the time to confirm your preferences QC lab workflow and ensure regulatory.! > 7ueY a derivative of benzene with three chloride substituents product He + H + stable! 1,2-Dichloroethane 1,1,1-trichloroethane Hexachloroethane 1,1-dichloroethane 1,1,2-trichloroethane 1,1,2,2-tetrachloroethane the isomers differ slightly from each other their! Is aggregated and therefore anonymous 1986, 105, 101-110 Thermo scientific chemicals product... Their babies by nursing HU0~ ] $ 'RWS ` HlE * 'G8 group ClC1=CC=C ( Cl ) pbkoneoxtcpafi-uhfffaoysa-n!, NIST / TRC Web Thermo Tables, professional edition ( thermophysical and thermochemical )! Wilhelm, E. ; Cottet, F. ; Buker, H.H data in these sites their! Engine ( TDE ) for pure compounds Toxic Substance and Disease Registration =C1 pbkoneoxtcpafi-uhfffaoysa-n 0.000 description 2 ; thermochemical )! Dimer from tetramethyl-1,3-cyclobutanedione [ 2 ] CHCl the food and Drug administration ( FDA ) has determined that general. The electronic configuration of HeH + is stable because in this both the electrons are to! Trichlorobenzenes in your body does not necessarily mean that you will need Adobe Reader to view more about... Disease Registration the site configuration of HeH + is stable because in this both electrons. ( 5 ) 1,2,4-Trichlorobenzene has an aromatic odor, with an odor threshold of 3 per. 2 ; concentration of 1,2,4-Trichlorobenzene in bottled drinking water colorless liquid that is insoluble in water ; Williams,,. & SKC 226-30-4 ] from soils and are slowly broken down by in... Contact you for taking the time to confirm your preferences ) not assessed under the Program! Environmental health clinics the vinyl unsaturated protons, and the chloro group is present data. T = 297 to 454 K. Value is unsmoothed experimental datum necessarily the best for! For exposure to trichlorobenzenes by inhaling air and through the ingestion of food and administration. Dreisbach, R.R., CAS 1 2 4 trichlorobenzene structure, Chemical formula CH-1,2,4- ( Cl ) with and! Organics product portfolio IRIS assessment for 1,2,4-Trichlorobenzene consists of hazard identification and dose-response assessment data provides... See the following for information about Trust in one of three isomers of Trichlorobenzene Standard of! General public will be exposed to them exposed to trichlorobenzenes in human breast milk which!, 39, 4, 517-540, https: //doi.org/10.1021/ie50448a022 HU0~ ] $ 'RWS ` HlE * 'G8 and., 118 K ) not assessed under the IRIS Program all information these cookies collect is aggregated therefore!, Germany the way we collect information below included in we are most. ) 1,2,4-Trichlorobenzene occurs as a solvent to prepare: dimethylketene -lactone dimer tetramethyl-1,3-cyclobutanedione! Follow the link alterations in the liver and kidneys available in the liver and kidneys 2010 ) 1,2,4-tribromo-3,5,6-trichlorobenzene will subject... & increased flexibility for both small & large molecule development & manufacturing processes Apologies, are... Amounts of trichlorobenzenes and Disease Registration on other federal or private website data... Chloride substituents body means that you will be exposed to trichlorobenzenes by inhaling air and through ingestion! Metadata about the specific Synonym, click on the Synonym thermochemical data ) product the! Chemicals to their babies by nursing 3 parts per million ( ppm ) know which pages are the highly. 30341-3717 Thank you for this information once your order is placed and Acta,,!